"Rust is not an oxidation (in a colloquial usage of terms)"
I am having a hard time with this. Rust is oxidation and is the result of the combination of iron with oxygen, regardless of source.
Is water necessary for rust to form? No. Only oxygen must be present. The process of rusting is the reaction of iron metal (Fe) combining with oxygen gas (O2) to form iron oxide (FeO or Fe2O3). Water (and salt) speed up this reaction a great deal, but oxygen is the only one that is necessary.
What am I missing.
Sorry, you are missing the actual knowledge of a process...you oversimplify the reactions, and the result is NOT necessary the oxides, but likely the hydroxides (
"In colloquial usage, the term is applied to red oxides, formed by the reaction of iron and oxygen
in the presence of water or air moisture. "
"Oxidation of iron metal
When impure(cast) iron is in contact with water, oxygen, or other strong oxidants and/or acids, it rusts. If salt is present as, for example, in salt water, it tends to rust more quickly, as a result of the electro-chemical reactions.
Iron metal is relatively unaffected by pure water or by dry oxygen. As with other metals, like aluminium, a tightly adhering oxide coating, a passivation layer, protects the bulk iron from further oxidation.
Thus, the conversion of the passivating iron oxide layer to rust results from the combined action of two agents, usually oxygen and water. Other degrading solutions are sulfur dioxide in water and carbon dioxide in water. Under these corrosive conditions, iron hydroxide species are formed. Unlike iron oxides, the hydroxides do not adhere to the bulk metal. As they form and flake off from the surface, fresh iron is exposed, and the corrosion process continues until either all of the iron is consumed or all of the oxygen, water, carbon dioxide, or sulfur dioxide in the system are removed or consumed.[2]"
you can start here..
http://en.wikipedia.org/wiki/Rust
the wikipedia is great for the purpose of quick educational reading...
Cheers,
P.S. Look, MS in Metallurgy and MS in Materials Science give me somewhat decent understanding of what the complex process that commonly called "rust" is...My English maybe rusty though...