My experience with a 23.5 XC90 T8 is for any drive over 30 miles or if after a sub-30 mile trip when we won't have time to fully recharge, is to be in hybrid mode in AUTO with our route planned out.
I find that if I have a route that includes getting to a highway, driving on a highway, then getting off of the highway, that the system is smart enough to not use battery (essentially hold mode) while on the highway.
Granted, I've only had it for about a month, but I've never had a route entered (usually round trip) with anything other than great efficiency. Usually, we're arriving back home with 1 mile left on the battery, the calculations are that good. To be fair, we haven't taken the car out for more than a 100 mile round trip drive. Hybrid in auto mode with navigation on did us well for the two 100 mile days. With trips around 60-70 miles, hybrid and auto is proven here to be perfect.
It's gotten to the point that for my 20 mile round trip each morning (kids to school, parent back home), I don't even bother with Pure mode. I just leave it in hybrid and set the round trip destination. Yes, setting a round trip is annoying with AAOS, but it gets me to the school and back, including a pretty big uphill drive in one direction, with about 15 miles left on the battery and almost no gas consumption based on the gas usage over the last month. The car assumes that you will be able to recharge when you get to the last destination, so if the total distance (and hill, speed, traffic calculations) say it can do it on all battery, it will try to.
I also almost always drive in B mode. I don't know if this actually is better for regenerative braking, but I sure do like the generally 1 petal driving.
Here's our last 574 miles, which has used just under 1/2 tank of gas based on the gauge. It calculated 71.1mpg, and with a 18.8 gallon tank that's just over 1/2 full, the calculation sounds right 574 / 8 or so. Now, a bunch of this driving is the 20 mile round trip to school each day, almost all on battery, and then we have enough time to fully recharge before being out and about, and the rest of the trips are mostly short. This includes either 2 or 3 70 mile round trips.
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